I have found the problem, like with alot of things that have not been starting up the guilty program is ad-watch (part of ad-aware pro) which protects the registry from being changed messed with to stop spyware, this sadly stopped start up things being changed so nothing i installed that sed it wud start up, wud start up. Got rid of ad-watch, don't need it. Reinstalled NOD32 and it starts up, thanks for your help guys!!!!