Spruce no longer exists, so he can't get a manual from them. And finding one on the net is virtually impossible unless you are willing to chance the torrent sites.
I did find a couple of guides to using it that might be helpful:
http://www.geocities.com/eaussie01au/maestro.html http://www.geocities.com/eaussie01au/maestro2.html http://www.doom9.org/index.html?/mpg/maestro.htm
You might consider
DVDLab Pro as a comparable substitute. Maestro is getting long in the tooth now, and has no support.