With DVD neXt COPY, I may be wrong, but I can't see any ability to split a DVD9 onto two SL backup media.
For those of you who remember the early days of backing up, the
original (before Express

or Platinum

) 321 Studios DVD-X-Copy (final version 1.5.2) did this beautifully. ...and even gave you a nice "Please Insert Disk 2" message at the end of Disk 1.
Whisperer