You problems are because bin/cue is a cd format and not a dvd format so neither nero nor alcohol will allow you to burn it directly to a blank dvd and, of course, the image is too large for a cd.

You may, and I stress may, be able to burn it with alcohol by mounting the image to alcohol's virtual drive and then just doing an ordinary copy from the mounted image.

If that doesn't work then I'm afraid you will have to get additional software that can either convert the image to an appropriate dvd format or that can burn the image directly to a dvd without conversion (I believe that both Dvd Decrypter and ImgBurn can do so).